I went through and interesting article here
Basically, what they state is that once you got the correspondence between biosignal ADC reading and maximum blood pressure, you can determine systolic and diastolic pressure by applying a linear equation on the minimum and maximum ADC reading for each heart beat
So I have a very simple (yet not optimal) solution to the problem of determining the systolic and diastolic pressure
The flow chart of the process for measuring blood pressure is as follow