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  • Author Author: Eavesdropper
  • Date Created: 31 Aug 2011 6:38 PM Date Created
  • Views 645 views
  • Likes 1 like
  • Comments 2 comments
  • research
  • alternative_energy
  • eavesdropper:dit
  • hydrogen
  • on_campus
  • fuel_cell
  • university
  • solar
  • innovation
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Clean hydrogen from an alloy and sunlight

Eavesdropper
Eavesdropper
31 Aug 2011
image
(System concept via University of Kentucky)
 
Hydrogen is not the abundant, free-energy, source everyone thinks it is. It has to be extracted from other compounds, like water. It takes a large amount of electricity to extract that hydrogen from other compounds. Right now, most of the hydrogen produced/collected in the word comes from non-renewable sources like natural gas and coal. However, this is about to change.
 
A new semiconductor alloy developed by the University of Kentucky and the University of Louisville that can generate hydrogen from water using only sunlight. Using state-of-the-art simulation software, the team found that an alloy formed by a 2% substitution of antimony (Sb) in gallium nitride (GaN) has the right electrical properties to allow for the photoelectrochemical splitting of water.
 
Project lead, Professor Madhu Menon, explained the development processes, "Previous research on PEC has focused on complex materials. We decided to go against the conventional wisdom and start with some easy-to-produce materials, even if they lacked the right arrangement of electrons to meet PEC criteria. Our goal was to see if a minimal 'tweaking' of the electronic arrangement in these materials would accomplish the desired results."
 
The efficiency and hydrogen volume that can be produced was not stated. Over time, a piece of the Sb-GaN alloy could quietly produce carbon-free  hydrogen somewhere. Even in small volume, it is a solid step towards cleaner energy.
 
The research is funded by the U.S. Department of Energy. The team is  led by Professors Madhu Menon and R. Michael Sheetz at the UK Center for Computational Sciences, and Professor Mahendra Sunkara and graduate student Chandrashekhar Pendyala at the UofL Conn Center for Renewable Energy Research. Their most recent findings were published Aug. 1 in the Physical Review Journal.
 
Eavesdropper
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  • Catwell
    Catwell over 14 years ago in reply to DAB

    Using sunlight is not anything new in electrolysis, but the volume of hydrogen produced is never mentioned.

     

    However, bypassing using more energy to split water than what you get back by using the sun is a great step.

     

    Someday soon all the advancements is fuelcell tech will combine into one very usable cell.

     

    Cabe

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  • DAB
    DAB over 14 years ago

    I agree, we need to see some numbers from this process to see if it is just a research curiosity or a promising technology.  If it pans out, it could be an excellent way to provide H2 and O2 for a fuel cell.  It all depends on cost and reliability.

     

    Nice idea though.

     

    DAB

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