Hi Cabe,
Well if you're a fan of tutorials, NI has put together quite a list of videos and written tutorials here: http://zone.ni.com/devzone/cda/tut/p/id/7466
That's probably a good place to start, just to get you the basics. Then I'd suggest looking at some of the built-in examples. From the LabVIEW "Getting Started" screen, just go to "Help" -> "Find Examples" and just start looking around. There are tons of well-documented VIs you can look through and perhaps even use in your application.
I also see that Pico has some LabVIEW drivers available in their Software Development Kit. I've taken a look at them and they're not exactly well-documented, but they might still be of some use.
If you have specific questions or tasks that you're trying to accomplish just let me know. I can whip up some example VIs for you that may be useful.